ETH Zurich scientists have identified a novel ferromagnetism in a custom-engineered moiré material, challenging traditional magnetic theories. This magnetism, based on electron spin alignment for kinetic energy minimization, offers new insights into quantum effects and solid-state magnetism.
For a magnet to stick to a fridge door, several physical effects must align perfectly. The magnetic moments of its electrons all point in the same direction, a phenomenon that occurs even without an external magnetic field.
This is due to the exchange interaction, a complex interplay of electrostatic repulsion among electrons and the quantum mechanical properties of electron spins, which generate magnetic moments. This mechanism explains why materials like iron and nickel are ferromagnetic, meaning they are permanently magnetic unless heated above a specific temperature.
At ETH Zurich, a team of researchers led by Ataç Imamoğlu at the Institute for Quantum Electronics and Eugene Demler at the Institute for Theoretical Physics has now detected a new type of ferromagnetism in an artificially produced material, in which the alignment of the magnetic moments comes about in a completely different way. They recently published their results in the scientific journal Nature.
Artificial material with electron filling
In Imamoğlu’s laboratory, PhD student Livio Ciorciaro, post-doc Tomasz Smolenski, and colleagues produced a special material by putting atomically thin layers of two different semiconductor materials (molybdenum diselenide and tungsten disulfide) on top of each other.
In the contact plane, the different lattice constants of the two materials – the separation between their atoms – leads to the formation of a two-dimensional periodic potential with a large lattice constant (thirty times larger than those of the two semiconductors), which can be filled with electrons by applying an electric voltage.
In the moiré material produced at ETH, the electron spins are disordered if there is exactly one electron per lattice site (left). As soon as there are more electrons than lattice sites (right) and pairs of electrons can form doublons (red), the spins align ferromagnetically as this minimizes the kinetic energy. Credit: ETH Zurich
“Such moiré materials have attracted great interest in recent years, as they can be used to investigate quantum effects of strongly interacting electrons very well,” says Imamoğlu. “However, so far very little was known about their magnetic properties.”
To investigate these magnetic properties, Imamoğlu and his coworkers measured whether for a certain electron filling the moiré material was paramagnetic, with its magnetic moments randomly oriented, or ferromagnetic. They illuminated the material with laser light and measured how strongly the light was reflected for different polarizations.
The polarization indicates in which direction the electromagnetic field of the laser light oscillates, and depending on the orientation of the magnetic moments – and hence the electron spins – the material will reflect one polarization more strongly than the other. From this difference, one can then calculate whether the spins point in the same direction or in different directions, from which the magnetization can be determined.
Striking evidence
By steadily increasing the voltage, the physicists filled the material with electrons and measured the corresponding magnetization. Up to a filling of exactly one electron per site of the moiré lattice (also known as a Mott insulator), the material remained paramagnetic. As the researchers kept adding electrons to the lattice, something unexpected happened: the material suddenly behaved very much like a ferromagnet.
“That was striking evidence for a new type of magnetism that cannot be explained by the exchange interaction,” Imamoğlu says. In fact, if the exchange interaction were responsible for the magnetism, that should have shown up also with fewer electrons in the lattice. The sudden onset, therefore, pointed towards a different effect.
Kinetic magnetism
Eugene Demler, in collaboration with post-doc Ivan Morera, finally had the crucial idea: they could be looking at a mechanism that the Japanese physicist Yosuke Nagaoka had theoretically predicted as early as 1966. In that mechanism, by making their spins point in the same direction the electrons minimize their kinetic energy (energy of motion), which is much larger than the exchange energy. I
n the experiment performed by the ETH researchers, this happens as soon as there is more than one electron per lattice site inside the moiré material. As a consequence, pairs of electrons can team up to form so-called doublons. The kinetic energy is minimized when the doublons can spread out over the entire lattice through quantum mechanical tunneling.
This, however, is only possible if the single electrons in the lattice align their spins ferromagnetically, as otherwise quantum mechanical superposition effects that enable the free expansion of the doublons are disturbed.
“Up to now, such mechanisms for kinetic magnetism have only been detected in model systems, for example in four coupled quantum dots,” says Imamoğlu, “but never in extended solid state systems like the one we use.”
As a next step, he wants to change the parameters of the moiré lattice in order to investigate whether the ferromagnetism is preserved for higher temperatures; in the current experiment that material still had to be cooled down to a tenth of a degree above absolute zero.
Reference: “Kinetic magnetism in triangular moiré materials” by L. Ciorciaro, T. Smoleński, I. Morera, N. Kiper, S. Hiestand, M. Kroner, Y. Zhang, K. Watanabe, T. Taniguchi, E. Demler and A. İmamoğlu, 15 November 2023, Nature.
DOI: 10.1038/s41586-023-06633-0
