Transmission electron microscope images of laboratory powder samples. Clockwise from top left, fullerene soot, black carbon aggregate from vehicle exhaust, Hematite-TD and Hematite-KJ. Credit: 2023 Moteki et al.
Scientists take the most accurate measurements yet of black carbon in the atmosphere.
Our industrialized civilization contributes a broad array of pollutants to the environment. A significant source of these pollutants is combustion, which leads to the production of aerosol particles, including black carbon. Although black carbon only forms a small percentage of these particles, its ability to absorb and retain heat, along with its potential to disrupt the heat-reflecting properties of surfaces like snow, makes it a matter of concern. Therefore, understanding how black carbon interacts with sunlight is critical. In a significant development, researchers have recently achieved the most precise measurement of black carbon’s refractive index, which could influence climate models.
There are numerous contributors to climate change, with some like carbon dioxide emissions from fossil fuel combustion, sulfur dioxide from cement production, and methane emissions from livestock farming being more commonly known. However, black carbon aerosols, also a byproduct of combustion, are less frequently discussed but carry significant importance. Essentially a form of soot, black carbon excels at absorbing sunlight and storing heat, consequently contributing to atmospheric warming.
At the same time, given dark colors are less effective at reflecting light and therefore heat, as black carbon covers lighter surfaces including snow, it reduces the potential of those surfaces to reflect heat back into space.
“Understanding the interaction between black carbon and sunlight is of fundamental importance in climate research,” said Assistant Professor Nobuhiro Moteki from the Department of Earth and Planetary Science at the University of Tokyo. “The most critical property of black carbon in this regard is its refractive index, basically how it redirects and disperses incoming light rays. However, existing measurements of black carbon’s refractive index were inaccurate. My team and I undertook detailed experiments to improve this. With our improved measurements, we now estimate that current climate models may be underestimating the absorption of solar radiation due to black carbon by a significant 16%.”
Transmission electron microscope images of ambient aerosols collected by an aerosol-impactor sampler installed on the research vessel Shinsei Maru. Red arrows indicate individual black carbon aggregates, most of which were mixed with sulfate (green arrows) and/or organic materials (light blue arrows). Credit: 2023 Moteki et al.
Previous measurements of the optical properties of black carbon were often confounded by factors such as lack of pure samples, or difficulties in measuring light interactions with particles of differing complex shapes. Moteki and his team improved this situation by capturing the black carbon particles in water, then isolating them with sulfates or other water-soluble chemicals. By isolating the particles, the team was better able to shine light on them and analyze the way they scatter, which gave researchers the data to calculate the value of refractive index.
“We measured the amplitude, or strength, and phase, or step, of the light scattered from black carbon samples isolated in water,” said Moteki. “This allowed us to calculate what is known as the complex refractive index of black carbon. Complex because rather than being a single number, it’s a value that contains two parts, one of which is ‘imaginary’ (concerned with absorption), though its impact is very, very real. Such complex numbers with imaginary components are actually very common in the field of optical science and beyond.”
As the new optical measurements of black carbon imply that current climate models are underestimating its contribution to atmospheric warming, the team hopes that other climate researchers and policymakers can make use of their findings. The method developed by the team to ascertain the complex refractive index of particles can be applied to materials other than black carbon. This allows for the optical identification of unknown particles in the atmosphere, ocean, or ice cores, and the evaluation of optical properties of powdered materials, not just those related to the ongoing problem of climate change.
Reference: “Constraining the complex refractive index of black carbon particles using the complex forward-scattering amplitude” by Nobuhiro Moteki, Sho Ohata, Atsushi Yoshida and Kouji Adachi, 3 May 2023, Aerosol Science and Technology.
DOI: 10.1080/02786826.2023.2202243
The study was funded by the Environmental Restoration and Conservation Agency, the Japan Society for the Promotion of Science (JSPS), and the Arctic Challenge for Sustainability ArCS II project.
